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Pyrazolyl- N -heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity

Page, Michael; Wagler, Jorg; Messerle, Barbara Ann


A series of bidentate 1-(1-pyrazolylmethyl)-substituted NHC ligands (13a-c, 14a-c and 15a-c) were synthesised with substituents of varying steric bulk incorporated adjacent to the donor atoms. These ligands were coordinated to rhodium(I) to give a series

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/b906724h


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