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Reactions of [Ru(CO) 2 (PPh 3 ) 3 ] with alkynylphosphonium salts: a phosphinoallene complex

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Ang, Wee; Cordiner, Richard; Hill, Anthony; Perry, Tamara; Wagler, Jorg

Description

[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a comple

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/57407
Source: Organometallics
DOI: 10.1021/om900621v

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