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Improving intramolecular hydroamination Rh(I) and Ir(I) catalysts through targeted ligand modification

Beeren, Sophie R.; Dabb, Serin L.; Edwards, Gavin; Smith, Matthew; Willis, Anthony; Messerle, Barbara Ann


A series of complexes containing the phosphino-pyrazolyl ligand 1-(2-(diphenylphosphino)phenyl)pyrazole (PyPhP) and 1-(2-(diphenylphosphino) ethyl)pyrazole (PyP) were synthesized: [Ir(PyPhP)(COD)]BPh4, [Ir(PyPhP)(CO)2]BPh4, Rh(PyPhP)(CO)Cl and Ir(PyPhP)(CO)Cl. The complexes Rh(PyP)(CO)OSO2CF3 and Rh(PyPhP)(CO) OSO2CF3 were also synthesized, using the parent complexes Rh(PyP)(CO)Cl and Rh(PyPhP)(CO)Cl. The solid-state structures of the new complexes were determined by X-ray diffraction analysis....[Show more]

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: New Journal of Chemistry
DOI: 10.1039/b9nj00759h


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