Synthesis, crystal structure and electronic properties of bis(N-2-bromophenyl-salicydenaminato)copper(II) complex
A new series of complexes of the type bis(N-substituted-salicydenaminato)copper(II) (1-9), have been synthesized and characterized by IR, UV-Vis and elemental analysis methods. The molecular structure of bis(N-2-bromophenyl-salicydenaminato)copper(II) (6), was determined using X-ray crystallography. There are two independent molecules in the structure. Each shows a neutral, mononuclear, four-coordinate, square-planar trans-Cu[N2O2] geometry and, in each, the Cu atom and the ligating atoms are...[Show more]
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