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A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex

Colebatch, Annie; Cordiner, Richard; Hill, Anthony; Nguyen, Thi Kelly; Shang, Rong; Willis, Anthony


Successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) 2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Organometallics
DOI: 10.1021/om900462p


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