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Reactions of [Ru(CO) 2 (PPh 3 ) 3 ] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination

Cordiner, Richard; Hill, Anthony; Wagler, Jorg

Description

[Ru(CO)2(PPh3)3] reacts with [Me 3SiC≡CPPh3]-OTf in the presence of moist [ nBu4N]F to provide the C-H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy betw

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/56920
Source: Organometallics
DOI: 10.1021/om9003384

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