Reactions of [Ru(CO) 2 (PPh 3 ) 3 ] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination
[Ru(CO)2(PPh3)3] reacts with [Me 3SiC≡CPPh3]-OTf in the presence of moist [ nBu4N]F to provide the C-H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy betw
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