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Effect of ring strain on disulfide electron attachment

Dumont, Elise; Loos, Pierre-Francois; Assfeld, Xavier

Description

The possibility of excess electron binding of a series of (bi)cyclic, ring-constrained disulfides, in gas phase was investigated by ab initio MP2/6-31+G** calculations. It is shown that ring strain favors electron attachment, as neutral compounds are very sensitive to angular and dihedral compressions: cyclic disulfides will preferentially undergo a spontaneous electron capture compared to linear analogs, with superior positive values for adiabatic electron affinity. Cyclisation effect is...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
URI: http://hdl.handle.net/1885/56866
Source: Chemical Physics Letters
DOI: 10.1016/j.cplett.2008.05.010

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