Coupled Li 1+ /Nb 5+ and O 2- /F - ordering on the Na and Cl sites of the average NaCl structure of Li 4 NbO 4 F
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Noren, Lasse; Withers, Raymond; Goossens, Darren; Elcombe, Margaret M; Kearley, Gordon
Description
The average, as well as the cation and anion 'disordered', crystal structure of Li4NbO4F has been carefully investigated via coupled neutron and X-ray powder diffraction studies as well as via electron diffraction studies. The existence of a spectacular highly structured diffuse intensity distribution in the latter provides strong evidence for coupled Li1+/Nb5+ and O2-/F- ordering on the Na and Cl sites of the average NaCl structure of Li4NbO4F. Bond valence sum calculations have been used to...[Show more]
Collections | ANU Research Publications |
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Date published: | 2009 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/56363 |
Source: | Journal of Solid State Chemistry |
DOI: | 10.1016/j.jssc.2009.02.015 |
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01_Noren_Coupled_Li_1+_/Nb_5+__and_O_2-_2009.pdf | 1.17 MB | Adobe PDF | Request a copy |
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