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Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [ trans -Cl(η 2 -dppe) 2 RuC≡C(4-C 6 H 4 X)] + (X = NO 2 , C(O)H, C(O)Me, F, H, OMe, NMe 2 ): Misleading Aspects of the ESR Anisotropy.

Gauthier, Nicolas; Tchouar, Noureddine; Justaud, Frederic; Argouarch, Gilles; Cifuentes, Marie; Toupet, Loic; Touchard, Daniel; Halet, Jean-Francois; Rigaut, Stephane; Costuas, Karine; Paul, Frederic; Humphrey, Mark


The bonding within the series of [trans-Cl(η2-dppe) 2RuC≡C(4-C6H4X)]n+ complexes (1-Xn+; n = 1, 0 and X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2) has been examined by IR, ESR, and UV-vis-near-IR spectroscopy together with computational modeling. A strong

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Organometallics
DOI: 10.1021/om801138q


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