Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [ trans -Cl(η 2 -dppe) 2 RuC≡C(4-C 6 H 4 X)] + (X = NO 2 , C(O)H, C(O)Me, F, H, OMe, NMe 2 ): Misleading Aspects of the ESR Anisotropy.
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Gauthier, Nicolas; Tchouar, Noureddine; Justaud, Frederic; Argouarch, Gilles; Cifuentes, Marie; Toupet, Loic; Touchard, Daniel; Halet, Jean-Francois; Rigaut, Stephane; Costuas, Karine; Paul, Frederic; Humphrey, Mark
Description
The bonding within the series of [trans-Cl(η2-dppe) 2RuC≡C(4-C6H4X)]n+ complexes (1-Xn+; n = 1, 0 and X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2) has been examined by IR, ESR, and UV-vis-near-IR spectroscopy together with computational modeling. A strong
Collections | ANU Research Publications |
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Date published: | 2009 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/56158 |
Source: | Organometallics |
DOI: | 10.1021/om801138q |
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