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Iridium tricarbido complexes via transmetallation with tricarbidomercurials

Dewhurst, Rian; Hill, Anthony; Willis, Anthony


The reactions of Vaska's complex with [Hg{CCCW(CO)2(L)} 2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)2(L)} 2(CO)(PPh3)2].

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/b900205g


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