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Dependence of the Properties of Cobalt(III) Cage Complex as a Function of the Derivatization of Amine Substituents

Sargeson, Alan; Lay, Peter


Control of redox properties of cobalt macrobicyclic hexaamine (cage) complexes by substituent modification is important for their use as electron-transfer agents, and the resultant derivatives can also change the lipophilicity of the complexes for a variety of biological and other applications. Such derivatization is also important for incorporating cage complexes into a range of redoxactive conjugates. Here, the derivatization of the amine groups in the 1 and 8 positions of [Co(sar)]3+ (sar =...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH09368


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