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Reactions of Co(III)-coordinated ornithine: towards inhibitors of the polyamine biosynthetic pathway

Clarkson, Andrea J; Blackman, Allan G.; Clark, Charles R; Sargeson, Alan


Treatment of the complex ,Δ-Λ[Co(en)2(S-ornithineH- κ2N,O)](CF3SO3)3 with SOCl2 in DMF gives a mixture of the expected imino complex [Co(en)2(2-iminoornithineH-2N,O)]3+ and the amidine complex [Co(en)2(5-{[(1E)-(dimethylamino)methylene]amino}-2- iminop

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH09315


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