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Synthesis and interconversions of digold(I), tetragold(I), digold(II), gold(I)-gold(III) and digold(III) complexes of fluorine-substituted aryl carbanions

Bennett, Martin; Bhargava, Suresh Kumar; Mirzadeh, Nedaossadat; Priver, Steven H; Wagler, Jorg; Willis, Anthony

Description

Treatment of [AuXL] (X = Br, L = AsPh3; X = Cl, L = tht) with the lithium or trimethyltin derivatives of the carbanions [2-C6F 4PPh2]- and [C6H3-n-F-2- PPh2]- (n = 5, 6) gives digold(i) complexes [Au 2(μ-carbanion)2] (carbanion = 2-C6F 4PPh22, C6H3-5-F-2

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/55576
Source: Dalton Transactions
DOI: 10.1039/b906769h

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