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On the nature of "RuCl(dmso) 2 {HB(mt) 3 }" (mt = methimazolyl)

Abernethy, Robyn; Hill, Anthony; Tshabang, Never; Willis, Anthony; Young, Rowan

Description

The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].

dc.contributor.authorAbernethy, Robyn
dc.contributor.authorHill, Anthony
dc.contributor.authorTshabang, Never
dc.contributor.authorWillis, Anthony
dc.contributor.authorYoung, Rowan
dc.date.accessioned2015-12-10T22:31:11Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/55428
dc.description.abstractThe high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Ruthenium compounds; Sodium; Dimethylsulfoxide; Hysteresis motors
dc.titleOn the nature of "RuCl(dmso) 2 {HB(mt) 3 }" (mt = methimazolyl)
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume28
dc.date.issued2009
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB328
local.type.statusPublished Version
local.contributor.affiliationAbernethy, Robyn, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationTshabang, Never, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationYoung, Rowan, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue2
local.bibliographicCitation.startpage488
local.bibliographicCitation.lastpage492
local.identifier.doi10.1021/om8007426
dc.date.updated2016-02-24T10:42:31Z
local.identifier.scopusID2-s2.0-61849146792
local.identifier.thomsonID000262608600015
CollectionsANU Research Publications

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