On the nature of "RuCl(dmso) 2 {HB(mt) 3 }" (mt = methimazolyl)
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Abernethy, Robyn; Hill, Anthony; Tshabang, Never; Willis, Anthony; Young, Rowan
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The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].
dc.contributor.author | Abernethy, Robyn | |
---|---|---|
dc.contributor.author | Hill, Anthony | |
dc.contributor.author | Tshabang, Never | |
dc.contributor.author | Willis, Anthony | |
dc.contributor.author | Young, Rowan | |
dc.date.accessioned | 2015-12-10T22:31:11Z | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/1885/55428 | |
dc.description.abstract | The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2]. | |
dc.publisher | American Chemical Society | |
dc.source | Organometallics | |
dc.subject | Keywords: Ruthenium compounds; Sodium; Dimethylsulfoxide; Hysteresis motors | |
dc.title | On the nature of "RuCl(dmso) 2 {HB(mt) 3 }" (mt = methimazolyl) | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 28 | |
dc.date.issued | 2009 | |
local.identifier.absfor | 039904 - Organometallic Chemistry | |
local.identifier.ariespublication | u4217927xPUB328 | |
local.type.status | Published Version | |
local.contributor.affiliation | Abernethy, Robyn, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Hill, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Tshabang, Never, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Young, Rowan, College of Physical and Mathematical Sciences, ANU | |
local.description.embargo | 2037-12-31 | |
local.bibliographicCitation.issue | 2 | |
local.bibliographicCitation.startpage | 488 | |
local.bibliographicCitation.lastpage | 492 | |
local.identifier.doi | 10.1021/om8007426 | |
dc.date.updated | 2016-02-24T10:42:31Z | |
local.identifier.scopusID | 2-s2.0-61849146792 | |
local.identifier.thomsonID | 000262608600015 | |
Collections | ANU Research Publications |
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