Skip navigation
Skip navigation

A donor-stabilized silanethione or a Si-substituted N -heterocyclic platinum carbene?

Brendler, Erica; Hill, Anthony; Wagler, Jorg

Description

The Si-substituted N-heterocyclic platinum or silanethione carbene for a donor-stabilized was studied. Synthesis were carried out under an inert atmosphere of dry nitrogen by using standard Schlenk techniques and dry solvents. The exploration of both, the synthesis and coordination chemistry of unknown methimazolylsilanes, led to an unprecedented rearrangement process to N-Si-substituted N-heterocyclic carbene (NHC). It was observed that this compound exhibits interesting structural features...[Show more]

dc.contributor.authorBrendler, Erica
dc.contributor.authorHill, Anthony
dc.contributor.authorWagler, Jorg
dc.date.accessioned2015-12-10T22:29:30Z
dc.identifier.issn0947-6539
dc.identifier.urihttp://hdl.handle.net/1885/54932
dc.description.abstractThe Si-substituted N-heterocyclic platinum or silanethione carbene for a donor-stabilized was studied. Synthesis were carried out under an inert atmosphere of dry nitrogen by using standard Schlenk techniques and dry solvents. The exploration of both, the synthesis and coordination chemistry of unknown methimazolylsilanes, led to an unprecedented rearrangement process to N-Si-substituted N-heterocyclic carbene (NHC). It was observed that this compound exhibits interesting structural features due to which, it is described as donor-stabilized silanethione. Oxidative addition of a methimazolylsilane to Pt0 provides easy access to novel N-hibited structural features consistent with donor-stabilized silanethione, thereby contributing to the pool of Si=X bonding patterns. NH moiety of the latter may allow for further substitution reactions thus, representing a convenient entrance into fictionalized NHC coordination chemistry, the applicability of which is subject to further investigations.
dc.publisherWiley-VCH Verlag GMBH
dc.sourceChemistry, A European Journal
dc.subjectKeywords: Chemical reactions; Platinum; Silicon; Stabilization; Substitution reactions; Bonding patterns; Carbene; Carbenes; Coordination chemistries; Donor stabilization; Dry nitrogens; Inert atmospheres; N-heterocyclic carbene; Oxidative addition; Rearrangement p Carbenes; Donor stabilization; Oxidative addition; Silanethione; Silicon
dc.titleA donor-stabilized silanethione or a Si-substituted N -heterocyclic platinum carbene?
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume14
dc.date.issued2008
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB314
local.type.statusPublished Version
local.contributor.affiliationBrendler, Erica, TU Bergakademie Freiberg
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, Freiberg University of Mining and Technology
local.description.embargo2037-12-31
local.bibliographicCitation.issue36
local.bibliographicCitation.startpage11300
local.bibliographicCitation.lastpage11304
local.identifier.doi10.1002/chem.200802032
dc.date.updated2016-02-24T10:42:27Z
local.identifier.scopusID2-s2.0-57649143491
local.identifier.thomsonID000262002900008
CollectionsANU Research Publications

Download

File Description SizeFormat Image
01_Brendler_A_donor-stabilized_2008.pdf211.54 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  22 January 2019/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator