Brendler, Erica; Hill, Anthony; Wagler, Jorg
The Si-substituted N-heterocyclic platinum or silanethione carbene for a donor-stabilized was studied. Synthesis were carried out under an inert atmosphere of dry nitrogen by using standard Schlenk techniques and dry solvents. The exploration of both, the synthesis and coordination chemistry of unknown methimazolylsilanes, led to an unprecedented rearrangement process to N-Si-substituted N-heterocyclic carbene (NHC). It was observed that this compound exhibits interesting structural features...[Show more]
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