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Insertion of CO 2 into the Ru-C bonds of cis - and trans -Ru(dmpe) 2 Me 2 (dmpe = Me 2 PCH 2 CH 2 PMe 2 )

Allen, Olivia R; Dalgarno, Scott J; Field, Leslie D; Jensen, Paul; Willis, Anthony

Description

reaction of cis-Ru(dmpe)2Me2 (1) and trans-Ru(dmpe)2Me2 (2) [dmpe = 1, 2-bis(dimethylphos- phino)ethane] with carbon dioxide was investigated. Addition of 3-4 atm of CO2 at 300 K to trans- Ru(dmpe)2Me2 (2) results in the formation of the expected methyl acetate complex trans-Ru(dmpe)2- (OCOMe)Me (3) and bis-acetate complex trans-Ru(dmpe)2(OCOMe)2 (5). Addition of 3-4 atm of CO2 at 300 K to cis-Ru(dmpe)2Me2 (1) leads to the formation of the expected methyl acetate complex cis- Ru(dmpe)2(OCOMe)Me...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/54892
Source: Organometallics
DOI: 10.1021/om801184k

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