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Asymmetric Synthesis of a Tertiary Arsine by Nucleophilic Addition to a Chiral Phosphine-Stabilized Arsenium Salt

Coote, Michelle; Krenske, Elizabeth; Porter, Keith; Weir, Michelle; Willis, Anthony; Zhou, Xiangting; Wild, Stanley (Bruce)


A new method for the asymmetric synthesis of As-chiral tertiary arsines is described. The addition at -95 °C of n-butyllithium to a dichloromethane solution of a phosphine-stabilized arsenium salt of the type (±)-[R 3P→AsMePh]PF6, where R3P is an enan

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Organometallics
DOI: 10.1021/om8006272


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