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Palladastannatrane - a Pd II →Sn IV Dative Bond

Wagler, Jorg; Hill, Anthony; Heine, Thomas

Description

The reaction of N-methyl-2-mercaptoimidazole (methimazole, Hmt) with NaN(SiMe3)2, [PdCl2(L)3] (L = PPh3, NCMe) and SnCl4 provides the novel tetrabicyclo[3.3.3.3.0] lantern compound [PdSn(μ-mt)4Cl 2] (1) in which a dative PdII→SnIV bond is housed within

dc.contributor.authorWagler, Jorg
dc.contributor.authorHill, Anthony
dc.contributor.authorHeine, Thomas
dc.date.accessioned2015-12-10T22:27:17Z
dc.identifier.issn1434-1948
dc.identifier.urihttp://hdl.handle.net/1885/54137
dc.description.abstractThe reaction of N-methyl-2-mercaptoimidazole (methimazole, Hmt) with NaN(SiMe3)2, [PdCl2(L)3] (L = PPh3, NCMe) and SnCl4 provides the novel tetrabicyclo[3.3.3.3.0] lantern compound [PdSn(μ-mt)4Cl 2] (1) in which a dative PdII→SnIV bond is housed within
dc.publisherWiley-VCH Verlag GMBH
dc.sourceEuropean Journal of Inorganic Chemistry
dc.subjectKeywords: Coordination modes; Heterometallic complexes; Metallastannatrane; Palladium; Tin
dc.titlePalladastannatrane - a Pd II →Sn IV Dative Bond
dc.typeJournal article
local.description.notesImported from ARIES
dc.date.issued2008
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB292
local.type.statusPublished Version
local.contributor.affiliationWagler, Jorg, Freiberg University of Mining and Technology
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHeine, Thomas, Jacobs University Bremen
local.description.embargo2037-12-31
local.bibliographicCitation.issue27
local.bibliographicCitation.startpage4225
local.bibliographicCitation.lastpage4229
local.identifier.doi10.1002/ejic.200800518
dc.date.updated2015-12-09T09:39:35Z
local.identifier.scopusID2-s2.0-53549111077
local.identifier.thomsonID000259943900004
CollectionsANU Research Publications

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