The regio- and stereo-selective formation of allylic chlorides during the Overman rearrangement of trichloroacetimidates derived from certain brominated conduritols
Microwave irradiation of imidate 2 at 165C affords a ∼3:1 mixture of the Overman rearrangement product 3 and the allylic chloride 4 (83% combined yield). Under the same conditions the deoxy-conduritol 6 gives a comparable mixture of compounds 7 and 8. T
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|Source:||Australian Journal of Chemistry|
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