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The regio- and stereo-selective formation of allylic chlorides during the Overman rearrangement of trichloroacetimidates derived from certain brominated conduritols

Matveenko, Maria; Willis, Anthony; Banwell, Martin

Description

Microwave irradiation of imidate 2 at 165C affords a ∼3:1 mixture of the Overman rearrangement product 3 and the allylic chloride 4 (83% combined yield). Under the same conditions the deoxy-conduritol 6 gives a comparable mixture of compounds 7 and 8. T

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/54130
Source: Australian Journal of Chemistry
DOI: 10.1071/CH08438

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