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Revised values of the bond valence parameters for [6] Sb(v)-O and [3-11] SB(III)-O

Mills, Stuart J; Christy, Andrew; Chen, E C-C; Raudsepp, Mati


Bond valence parameters r0 and b have been re-determined for [3-11]Sb(III)-O and [6]Sb(V)-O, utilising crystal structures of natural and inorganic compounds from the Inorganic Crystal Structure Database. Bond valence parameters for Sb(III) were obtained from a best-fit r0-b curve for 242 independent SbOn polyhedra. For [6]Sb(V), a curve of best fitting r0-b pairs was determined by fitting to 207 independent SbO6 octahedra; b was then determined by optimising bond valence sums on the oxygens of...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Zeitschrift fur Kristallographie
DOI: 10.1524/zkri.2009.1166


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