Skip navigation
Skip navigation

C -Glycosylation of oxygenated naphthols with 3-dimethylamino-2,3,6-trideoxy-L-arabino-hexopyranose and 3-azido-2,3,6-trideoxy-D-arabino-hexopyranose

Brimble, Margaret A; Davey, Roger M; McLeod, Malcolm; Murphy, Maureen

Description

In connection with studies directed towards the synthesis of the pyranonaphthoquinone antibiotic medermycin, C-aryl glycosides were prepared by C-glycosylation of naphthols with glycosyl donors. Boron trifluoride diethyl etherate proved to be a suitable Lewis acid to promote the C-glycosylation, and use of the azido glycosyl donor proved more successful than using the dimethylamino glycosyl donor. 5-Hydroxy-1,4-dimethoxynaphthalene underwent facile C-glycosylation with two particular glycosyl...[Show more]

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/53334
Source: Australian Journal of Chemistry
DOI: 10.1071/CH02236

Download

File Description SizeFormat Image
01_Brimble_C_-Glycosylation_of_oxygenated_2003.pdf256.05 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  23 August 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator