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Synthesis of the β-hydroxydopa-γ-hydroxy-δ-sulfinylnorvaline component of ustiloxins A and B

Hunter, Luke; McLeod, Malcolm; Hutton, Craig A

Description

The dopa-sulfinylnorvaline component of ustiloxins A and B has been prepared using an Evans salen-Al-catalysed aldol reaction with a 6-mercaptoisovanillin derivative, followed by incorporation of the norvaline group and asymmetric oxidation of the resulting sulfide to give the corresponding sulfoxide.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/53057
Source: Organic and Biomolecular Chemistry
DOI: 10.1039/b418876d

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