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Selective manipulation of steroid hydroxyl groups with boronate esters: efficient access to antigenic C-3 linked steroid-protein conjugates and steroid sulfate standards for drug detection

Hungerford, Natasha; McKinney, Andrew; Stenhouse, Allen M; McLeod, Malcolm


The temporary protection of 17α-alkyl-5α-androstane-3β, 16β,17β triols as boronate esters is an efficient method for their regioselective functionalisation. This has been applied to the synthesis of protein-steroid conjugates 7-10 suitable for the de

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Organic and Biomolecular Chemistry
DOI: 10.1039/b610499a


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