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Synthesis of Cp* iridium and rhodium complexes containing bidentate sp(2)-N-donor ligands and counter-anions [Cp*MCl3](-)

Kennedy, Danielle F.; Messerle, Barbara Ann; Smith, Matthew

Description

Complexes of the type [Cp*MCl(N-N)][X] (M = Rh and Ir) have been synthesised, where N-N is a series of bidentate ligands with sp2 N-donors: bis(pyrazol-1-yl)methane (bpm), bis(1-methylimidazol-2-yl)methane (bim), bis(3,5-dimethylpyrazol-1-yl)methane (dmbpm), bis(1-methylimidazol-2-yl) ketone (bik), bis(2,4,6-trimethylphenylimino)acenapthene (mesBIAN), 2,4,6-trimethylphenylimino-(1-methyl-2-imidazolyl)methane (mesim-mim), and X = Cl-, BF4- and the unusual anion [Cp*MCl3]-. All of these complexes...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/52772
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.200600735

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