Synthesis of Cp* iridium and rhodium complexes containing bidentate sp(2)-N-donor ligands and counter-anions [Cp*MCl3](-)
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Kennedy, Danielle F.; Messerle, Barbara Ann; Smith, Matthew
Description
Complexes of the type [Cp*MCl(N-N)][X] (M = Rh and Ir) have been synthesised, where N-N is a series of bidentate ligands with sp2 N-donors: bis(pyrazol-1-yl)methane (bpm), bis(1-methylimidazol-2-yl)methane (bim), bis(3,5-dimethylpyrazol-1-yl)methane (dmbpm), bis(1-methylimidazol-2-yl) ketone (bik), bis(2,4,6-trimethylphenylimino)acenapthene (mesBIAN), 2,4,6-trimethylphenylimino-(1-methyl-2-imidazolyl)methane (mesim-mim), and X = Cl-, BF4- and the unusual anion [Cp*MCl3]-. All of these complexes...[Show more]
Collections | ANU Research Publications |
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Date published: | 2007 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/52772 |
Source: | European Journal of Inorganic Chemistry |
DOI: | 10.1002/ejic.200600735 |
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