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POSS Fulleropyrrolidines

Clarke, David J.; Clarke, Stephen; Matisons, Janis G.; Simon, George R.; Samoc, Anna; Samoc, Marek


The first reported examples of polyhedral oligomeric silsesquioxane (POSS) cages containing a fulleropyrrolidine species are reported herein. Monosubstituted POSS-dioxalane species were synthesized through the hydrosilylation of a silyl-dioxalane with mono-vinyl substituted POSS. Subsequent deprotection yielded the desired aldehyde functionality. An alternative synthetic pathway, involving the nucleophilic substitution of mono-benzyl chloride POSS with 4-hydroxybenzaldehyde yielded the desired...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Conference paper
Source: Proceedings of the 2008 International Conference on Nanoscience and Nanotechnology
DOI: 10.1109/ICONN.2008.4639234


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