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Fluctuation theorems

Sevick, Edith M; Ranganathan, Prabhakar; Williams, Stephen; Searles, Debra


Fluctuation theorems, developed over the past 15 years, have resulted in fundamental breakthroughs in our understanding of how irreversibility emerges from reversible dynamics and have provided new statistical mechanical relationships for free-energy changes. They describe the statistical fluctuations in time-averaged properties of many-particle systems such as fluids driven to nonequilibrium states and provide some of the few analytical expressions that describe nonequilibrium states....[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Annual Review of Physical Chemistry
DOI: 10.1146/annurev.physchem.58.032806.104555


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