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Carbonyl substitution chemistry of some trimetallic transition metal cluster complexes with polyfunctional ligands

Byrne, Lindsay T.; Hondow, Nicole S.; Koutsantonis, George; Skelton, Brian; Torabi, A. Asgar; White, Allan; Wild, Stanley (Bruce)


The trimetallic clusters [Ru3(CO)10(dppm)], [Ru3(CO)12] and [RuCo2(CO)11] react with a number of multifunctional secondary phosphine and tertiary arsine ligands to give products consequent on carbonyl substitution and, in the case of the secondary phosphines, PH activation. The reaction with the unresolved mixed P/S donor, 1-phenylphosphino-2-thio(ethane), HSCH2CH2PHPh ({double bond, long} LH2), gave two products under various conditions which have been characterised by spectroscopic and...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2008.01.040


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