Near linear Ta-H-B geometry: [TaCl 2 ( η -C 5 Me 5 ){ κ  3  H , S , S '-H 2 B(methimazolyl) 2 }]

Hill, Anthony; Smith, Matthew; Wagler, Jorg

doi:10.1021/om7008099

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Near linear Ta-H-B geometry: [TaCl 2 ( η -C 5 Me 5 ){ κ 3 H , S , S '-H 2 B(methimazolyl) 2 }]

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Hill, Anthony; Smith, Matthew; Wagler, Jorg

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The reaction of [TaCl4(η-C5Me5)] with Na[H2B(mt)2] provides the tantalum(IV) complex [TaCl 2(η-C5Me5){H2B(mt) 2}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.

dc.contributor.author	Hill, Anthony
dc.contributor.author	Smith, Matthew
dc.contributor.author	Wagler, Jorg
dc.date.accessioned	2015-12-10T22:21:02Z
dc.identifier.issn	0276-7333
dc.identifier.uri	http://hdl.handle.net/1885/52205
dc.description.abstract	The reaction of [TaCl4(η-C5Me5)] with Na[H2B(mt)2] provides the tantalum(IV) complex [TaCl 2(η-C5Me5){H2B(mt) 2}], the crystal structure of which reveals an essentially linear Ta-H-B interaction.
dc.publisher	American Chemical Society
dc.source	Organometallics
dc.subject	Keywords: Computational geometry; Crystal structure; Linear Ta-H-B interaction; Ta-H-B geometry; Tantalum compounds
dc.title	Near linear Ta-H-B geometry: [TaCl 2 ( η -C 5 Me 5 ){ κ 3 H , S , S '-H 2 B(methimazolyl) 2 }]
dc.type	Journal article
local.description.notes	Imported from ARIES
local.identifier.citationvolume	27
dc.date.issued	2008
local.identifier.absfor	039904 - Organometallic Chemistry
local.identifier.ariespublication	u4217927xPUB241
local.type.status	Published Version
local.contributor.affiliation	Hill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliation	Smith, Matthew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliation	Wagler, Jorg, College of Physical and Mathematical Sciences, ANU
local.description.embargo	2037-12-31
local.bibliographicCitation.issue	9
local.bibliographicCitation.startpage	2137
local.bibliographicCitation.lastpage	2140
local.identifier.doi	10.1021/om7008099
dc.date.updated	2015-12-09T08:53:22Z
local.identifier.scopusID	2-s2.0-44449170486
local.identifier.thomsonID	000255373400025
Collections	ANU Research Publications

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Near linear Ta-H-B geometry: [TaCl 2 ( η -C 5 Me 5 ){ κ 3 H , S , S '-H 2 B(methimazolyl) 2 }]

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