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Alkynylselenolatoalkylidynes: [Mo(≡CSeC≡CR)(CO) 2 {HB(pzMe 2 ) 3 }] (R = CMe 3 , SiMe 3 ; pzMe 2 = 3,5-Dimethylpyrazol-1-yl)

Caldwell, Lorraine; Hill, Anthony; Rae, A David; Willis, Anthony


The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylselenolates (LiSeC=CR; R = CMe3, SiMe3) provide the alkynylselenolatoalkylidyne complexes [Mo(≡CSeC≡CR)(CO) 2{HB(pzMe2)3}]. Cobalt carbonyl adds across

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Organometallics
DOI: 10.1021/om7008342


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