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Polyhedral oligomeric silsesquioxane bound fulleropyrrolidines

Clarke, David J.; Matisons, Janis G.; Simon, George R.; Samoc, Marek; Samoc, Anna


The first reported examples of polyhedral oligomeric silsesquioxane (POSS) cages containing a fulleropyrrolidine species are reported herein. Monosubstituted POSS-dioxalane species were synthesized through the hydrosilylation of a silyl-dioxalane with mono-vinyl substituted POSS. Subsequent deprotection yielded the desired aldehyde functionality. An alternative synthetic pathway, involving the nucleophilic substitution of mono-benzyl chloride POSS with 4-hydroxybenzaldehyde yielded the desired...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Applied Organometallic Chemistry
DOI: 10.1002/aoc.1425


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