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Synthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl-Alkenyl and Thioacyl Complexes of Ruthenium(II)

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Cowley, Andrew R; Hector, Andrew L; Hill, Anthony; White, Andrew J P; Williams, David; Wilton-Ely, James

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The reactions of [RuHCl(CS)(PPh3)3] with R 1C≡CR2 (R1 = R2 = H, Ph, CO2Me; R1 = H, R2 = C6H 4Me-4; R1 = C≡CPh, R2 = Ph) lead to the five- or six-coordinate (R1 = R2 = CO2Me) σ-alkenyl complexes [Ru(CR1=CHR2)Cl(CS)(PPh 3)2], the stilbenyl derivative b

dc.contributor.authorCowley, Andrew R
dc.contributor.authorHector, Andrew L
dc.contributor.authorHill, Anthony
dc.contributor.authorWhite, Andrew J P
dc.contributor.authorWilliams, David
dc.contributor.authorWilton-Ely, James
dc.date.accessioned2015-12-10T22:14:26Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/50302
dc.description.abstractThe reactions of [RuHCl(CS)(PPh3)3] with R 1C≡CR2 (R1 = R2 = H, Ph, CO2Me; R1 = H, R2 = C6H 4Me-4; R1 = C≡CPh, R2 = Ph) lead to the five- or six-coordinate (R1 = R2 = CO2Me) σ-alkenyl complexes [Ru(CR1=CHR2)Cl(CS)(PPh 3)2], the stilbenyl derivative b
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Carbon monoxide; Crystal structure; Synthesis (chemical); Thermolysis; Diphenylacetylene; Stilbenyl derivatives; Ruthenium compounds
dc.titleSynthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl-Alkenyl and Thioacyl Complexes of Ruthenium(II)
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume26
dc.date.issued2007
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB201
local.type.statusPublished Version
local.contributor.affiliationCowley, Andrew R, University of Oxford
local.contributor.affiliationHector, Andrew L, Imperial College London
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, Andrew J P, Imperial College London
local.contributor.affiliationWilliams, David, Imperial College London
local.contributor.affiliationWilton-Ely, James, University College London
local.description.embargo2037-12-31
local.bibliographicCitation.issue25
local.bibliographicCitation.startpage6114
local.bibliographicCitation.lastpage6125
local.identifier.doi10.1021/om700518m
dc.date.updated2015-12-09T08:07:56Z
local.identifier.scopusID2-s2.0-37249082099
CollectionsANU Research Publications

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