Synthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl-Alkenyl and Thioacyl Complexes of Ruthenium(II)
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Cowley, Andrew R; Hector, Andrew L; Hill, Anthony; White, Andrew J P; Williams, David; Wilton-Ely, James
Description
The reactions of [RuHCl(CS)(PPh3)3] with R 1C≡CR2 (R1 = R2 = H, Ph, CO2Me; R1 = H, R2 = C6H 4Me-4; R1 = C≡CPh, R2 = Ph) lead to the five- or six-coordinate (R1 = R2 = CO2Me) σ-alkenyl complexes [Ru(CR1=CHR2)Cl(CS)(PPh 3)2], the stilbenyl derivative b
Collections | ANU Research Publications |
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Date published: | 2007 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/50302 |
Source: | Organometallics |
DOI: | 10.1021/om700518m |
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