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Radical Ring-Opening Polymerization of Phosphorus Heterocylces: Computational Design of Suitable Phosphetane Monomers

Coote, Michelle; Hodgson, Jennifer; Krenske, Elizabeth; Namazian, Mansoor; Wild, Stanley (Bruce)


High-level ab initio calculations have been used to determine the propensities of various phosphetanes towards radical ring-opening polymerization. At the G3(MP2)-RAD level of theory, the propagation rate constants of 1-methylphosphetane (7.5 × 104 L mol

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH07121


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