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A Molecular Orbital Rationalization of Ligand Effects in N2 Activation

Ariafard, Alireza; Brookes, Nigel J; Stranger, Robert; Yates, Brian F


Molecular orbital theory has been used to study a series of [(μ-N 2)-{ML3}2] complexes as models for dinitrogen activation, with M = Mo, Ta, W, Re and L = NH2, PH2, AsH2, SbH2 and N(BH2)2. The main aims of this study have been to provide a thorough elect

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Chemistry, A European Journal
DOI: 10.1002/chem.200800235


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