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Modulation of Third-Order Nonlinear Optical Properties by Backbone Modification of Polymeric Pillared-Layer Heterometallic Clusters

Zhang, Chi; Cao, Yuan; Zhang, Jinfang; Meng, Suci; Matsumoto, Tsuyosh; Song, Yinglin; Ma, Jing; Chen, Zhaoxu; Tatsumi, Kazuyuki; Humphrey, Mark

Description

A study was conducted to demonstrate the synthesis of three structurally interesting polymeric heterothiometallic clusters with 3D pillar-layer- alternating honeycomb structure. The study observed that the connecting pillar ligands can modulate the NLO behavior of cluster polymers by π-electron delocalization. The study also used a density functional theory (DFT) calculations to determine the influence of bridging ligands on the electronic structure. It was observed during the study that the...[Show more]

dc.contributor.authorZhang, Chi
dc.contributor.authorCao, Yuan
dc.contributor.authorZhang, Jinfang
dc.contributor.authorMeng, Suci
dc.contributor.authorMatsumoto, Tsuyosh
dc.contributor.authorSong, Yinglin
dc.contributor.authorMa, Jing
dc.contributor.authorChen, Zhaoxu
dc.contributor.authorTatsumi, Kazuyuki
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-08T22:48:37Z
dc.identifier.issn0935-9648
dc.identifier.urihttp://hdl.handle.net/1885/38409
dc.description.abstractA study was conducted to demonstrate the synthesis of three structurally interesting polymeric heterothiometallic clusters with 3D pillar-layer- alternating honeycomb structure. The study observed that the connecting pillar ligands can modulate the NLO behavior of cluster polymers by π-electron delocalization. The study also used a density functional theory (DFT) calculations to determine the influence of bridging ligands on the electronic structure. It was observed during the study that the one-pot self-assembly can avoid the incorporation of terminal halogen atoms or large counter-ions. An infinite 3D honeycomb framework can be observed during crystallographic analysis. The UV-vis spectra also revealed that a low linear absorption took place in the visible and near-IR region.
dc.publisherWiley-VCH Verlag GMBH
dc.sourceAdvanced Materials
dc.subjectKeywords: ABS resins; Absorption; Density functional theory; Electronic structure; Honeycomb structures; Modulation; Optical properties; A densities; Bridging ligands; Crystallographic analyses; Delocalization; Halogen atoms; Heterometallic clusters; Linear absorpt
dc.titleModulation of Third-Order Nonlinear Optical Properties by Backbone Modification of Polymeric Pillared-Layer Heterometallic Clusters
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume20
dc.date.issued2008
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu9911292xPUB161
local.type.statusPublished Version
local.contributor.affiliationZhang, Chi, Nanjing University of Science and Technology
local.contributor.affiliationCao, Yuan , Nanjing University of Science and Technology
local.contributor.affiliationZhang, Jinfang, University of Science
local.contributor.affiliationMeng, Suci , Nanjing University
local.contributor.affiliationMatsumoto, Tsuyosh, Nagoya University
local.contributor.affiliationSong, Yinglin, Suzhou University
local.contributor.affiliationMa, Jing, Nanjing University
local.contributor.affiliationChen, Zhaoxu, Nanjing University
local.contributor.affiliationTatsumi, Kazuyuki, Nagoya University
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.startpage1870
local.bibliographicCitation.lastpage1875
local.identifier.doi10.1002/adma.200702645
dc.date.updated2016-02-24T12:14:03Z
local.identifier.scopusID2-s2.0-55049097359
local.identifier.thomsonID000256846300010
CollectionsANU Research Publications

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