Modulation of Third-Order Nonlinear Optical Properties by Backbone Modification of Polymeric Pillared-Layer Heterometallic Clusters
A study was conducted to demonstrate the synthesis of three structurally interesting polymeric heterothiometallic clusters with 3D pillar-layer- alternating honeycomb structure. The study observed that the connecting pillar ligands can modulate the NLO behavior of cluster polymers by π-electron delocalization. The study also used a density functional theory (DFT) calculations to determine the influence of bridging ligands on the electronic structure. It was observed during the study that the...[Show more]
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