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Modulation of Third-Order Nonlinear Optical Properties by Backbone Modification of Polymeric Pillared-Layer Heterometallic Clusters

Zhang, Chi; Cao, Yuan; Zhang, Jinfang; Meng, Suci; Matsumoto, Tsuyosh; Song, Yinglin; Ma, Jing; Chen, Zhaoxu; Tatsumi, Kazuyuki; Humphrey, Mark


A study was conducted to demonstrate the synthesis of three structurally interesting polymeric heterothiometallic clusters with 3D pillar-layer- alternating honeycomb structure. The study observed that the connecting pillar ligands can modulate the NLO behavior of cluster polymers by π-electron delocalization. The study also used a density functional theory (DFT) calculations to determine the influence of bridging ligands on the electronic structure. It was observed during the study that the...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Advanced Materials
DOI: 10.1002/adma.200702645


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