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Silicon Surface-Bound Redox-Active ConjugatedWires Derived From Mono- and Dinuclear Iron(II)and Ruthenium(II) Oligo(phenyleneethynylene) Complexes

Gauthier, Nicolas; Argouarch, Gilles; Paul, Frederic; Toupet, L; Ababou-Girard, Soraya; Sabbah, Hussein; Hapiot, Philippe; Fabre, Bruno; Humphrey, Mark


A study has demonstrated the successful covalent assembly of electron-rich mononuclear Fe(II) (21-23) and dinuclear Fe(II) Ru(II) acetylides on monocrystalline silicon surfaces following a novel approach. The experimentation shows that electron-rich mononuclear Fe(II) (2n) or dinuclear Fe(II)/Ru(II) (3) acetylide complexes can be grafted onto hydrogenated silicon surfaces under very mild conditions and following a simple one-step photochemical procedure. These redox-active organometallic...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Advanced Materials
DOI: 10.1002/adma.200800324


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