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Cross-Coupling for Cross-Conjugation: Practical Synthesis and Diels-Alder Reactions of [3]Dendralenes

Bradford, Tanya; Payne, Alan; Willis, Anthony; Paddon-Row, Michael; Sherburn, Michael


(Chemical Equation Presented) The parent [3]dendralene and 2-substituted [3]dendralenes are made easily through cross-coupling reactions. Contrary to some earlier reports, [3]dendralene is sufficiently stable to be handled using standard synthetic methods. These compounds allow the one-step stereoselective construction of polycyclic frameworks through reactions with dienophiles. Site selectivity and stereoselectivity in Diels-Alder reactions with dienophiles are generally not influenced by the...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol7021998


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