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High-nuclearity ruthenium carbonyl cluster chemistry. 8: Phosphine activation, CO insertion, and deruthenation at a phosphido cluster - X-ray structures of [ppn][Ru 8 (μ 8 -P)(μ-CO) 2 (CO) 20 ] and [ppn][Ru 7 (μ 7 -P)(μ-η 2 -OCPh)(μ-PPh 2 )(μ-CO) (CO) 17 ]

Randles , Michael; Willis, Anthony; Cifuentes, Marie; Humphrey, Mark


Reaction of the square antiprismatic cluster [ppn][Ru8(μ8-P)(μ-CO)2(CO)20] [ppn = bis(triphenylphosphoranylidene)ammonium] with triphenylphosphine proceeds by loss of one cluster core vertex, phosphine P-C cleavage, and CO insertion into the putative Ru

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2007.03.040


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