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Intramolecular Optical Electron Transfer in Mixed-Valent Dinuclear Iron-Ruthenium Complexes Featuring a 1,4-Diethynylaryl Spacer

Gauthier, Nicolas; Olivier, C.; Rigaut, Stephane; Touchard, Daniel; Roisnel, Thierry; Paul, Frederic; Humphrey, Mark

Description

The ground-state electronic structure and the lowest-lying excited states of the cationic mixed-valent dinuclear complexes [(η2-dppe) (η5-C5Me5)Fe[C≡C-1,4-(C 6H4)C≡C]Ru(η2-dppe) 2(X)][PF6] (X = Cl, 2; X = C≡C(4-C6H 4NO2), 5) are discussed, with p

dc.contributor.authorGauthier, Nicolas
dc.contributor.authorOlivier, C.
dc.contributor.authorRigaut, Stephane
dc.contributor.authorTouchard, Daniel
dc.contributor.authorRoisnel, Thierry
dc.contributor.authorPaul, Frederic
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-08T22:44:51Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/37581
dc.description.abstractThe ground-state electronic structure and the lowest-lying excited states of the cationic mixed-valent dinuclear complexes [(η2-dppe) (η5-C5Me5)Fe[C≡C-1,4-(C 6H4)C≡C]Ru(η2-dppe) 2(X)][PF6] (X = Cl, 2; X = C≡C(4-C6H 4NO2), 5) are discussed, with p
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Charge transfer; Electron transitions; Excited states; Electron transfer; Intramolecular electron transfer; Iron centers; Organometallics
dc.titleIntramolecular Optical Electron Transfer in Mixed-Valent Dinuclear Iron-Ruthenium Complexes Featuring a 1,4-Diethynylaryl Spacer
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume27
dc.date.issued2008
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu9911292xPUB150
local.type.statusPublished Version
local.contributor.affiliationGauthier, Nicolas, Universite de Rennes
local.contributor.affiliationOlivier, C., Universite de Rennes 1
local.contributor.affiliationRigaut, Stephane, UniVersite de Rennes 1
local.contributor.affiliationTouchard, Daniel, Universite de Rennes 1
local.contributor.affiliationRoisnel, Thierry, Universite de Rennes
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPaul, Frederic, Universite de Rennes
local.description.embargo2037-12-31
local.bibliographicCitation.startpage1063
local.bibliographicCitation.lastpage1072
local.identifier.doi10.1021/om700584m
dc.date.updated2015-12-08T10:48:17Z
local.identifier.scopusID2-s2.0-41749104002
local.identifier.thomsonID000254085000011
CollectionsANU Research Publications

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