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Intramolecular Optical Electron Transfer in Mixed-Valent Dinuclear Iron-Ruthenium Complexes Featuring a 1,4-Diethynylaryl Spacer

Gauthier, Nicolas; Olivier, C.; Rigaut, Stephane; Touchard, Daniel; Roisnel, Thierry; Paul, Frederic; Humphrey, Mark


The ground-state electronic structure and the lowest-lying excited states of the cationic mixed-valent dinuclear complexes [(η2-dppe) (η5-C5Me5)Fe[C≡C-1,4-(C 6H4)C≡C]Ru(η2-dppe) 2(X)][PF6] (X = Cl, 2; X = C≡C(4-C6H 4NO2), 5) are discussed, with p

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Organometallics
DOI: 10.1021/om700584m


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