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Electron Compton scattering from methane and methane-d4

Cooper, G.; Hitchcock, Adam Percival; Chatzidimitriou-Dreismann, C; Vos, Maarten

Description

Quasi-elastic electron scattering at high-momentum transfer was measured for CH4 and CD4 in the gas phase. At high-momentum transfer, two scattering peaks are observed in each molecule. We interpret the splitting as due to independent Compton scattering from each nucleus, such that, at an impact energy of 2 keV and 100° scattering angle, the peaks for the C and H in CH4 are split by 2.1 eV while those associated with the C and D in CD4 are split by 1.1 eV. These splittings are in agreement with...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/37532
Source: Journal of Electron Spectroscopy and Related Phenomena
DOI: 10.1016/j.elspec.2006.11.001

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