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Towards the Total Synthesis of Vibsanin E, 15-O Methylcyclovibsanin B, 3-Hydroxyvibsanin E, Furanovibsanin A, and 3-O Methylfuranovibsanin A

Schwartz, Brett; Tilly, David P; Heim, Ralf; Wiedemann, Stefan; Williams, Craig; Bernhardt, Paul


Studies detailing synthetic approaches to a variety of biosynthetically related vibsanin-type diterpenes (i.e. vibsanin E, 15-O-methylcyclovibsanin B, 3-hydroxy-vibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A) are discussed. Biogenetically modelled approaches are coupled with an investigation of classical and modern six- to seven-membered ring-expansion protocols, which gain access to the central core of these natural products.

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: European Journal of Organic Chemistry
DOI: 10.1002/ejoc.200600246


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