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Two-photon and Three-photon Absorption in an Organometallic Dendrimer

Samoc, Marek; Morrall, Joseph; Dalton, Gulliver; Cifuentes, Marie; Humphrey, Mark

Description

Three at a time: The wavelength dependence of nonlinear absorption and non-linear refraction of a peripherally nitrophenylethynyl-functionalized first-generation arylethynylruthenium dendrimer (see picture; dppe = 1,2-bis(diphenylphosphanyl)ethane) was examined in the range 625-1500 nm by employing fs pulses. The compound is a strong two-photon absorber in the range 600-800 nm and an exceptional three-photon absorber in the range 1100-1200 nm. (Chemical Equation Presented).

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/35295
Source: Angewandte Chemie International Edition
DOI: 10.1002/anie.200602341

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