Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli
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Dalton, Gulliver; Cifuentes, Marie; Petrie, Simon; Stranger, Robert; Samoc, Marek; Humphrey, Mark
Description
The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.
Collections | ANU Research Publications |
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Date published: | 2007 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/34505 |
Source: | Journal of the American Chemical Society |
DOI: | 10.1021/ja074205k |
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01_Dalton_Independent_Switching_of_Cubic_2007.pdf | 68.81 kB | Adobe PDF | Request a copy |
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