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Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli

Dalton, Gulliver; Cifuentes, Marie; Petrie, Simon; Stranger, Robert; Samoc, Marek; Humphrey, Mark


The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja074205k


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