Skip navigation
Skip navigation

Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli

Dalton, Gulliver; Cifuentes, Marie; Petrie, Simon; Stranger, Robert; Humphrey, Mark; Samoc, Marek

Description

The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/34505
Source: Journal of the American Chemical Society
DOI: 10.1021/ja074205k

Download

File Description SizeFormat Image
01_Dalton_Independent_Switching_of_Cubic_2007.pdf68.81 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  20 July 2017/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator