Probing the Electronic Structures of Coordination Compounds by Transient Spectral Hole-Burning. Applications to Specifically Deuterated [Ru(bpy)3]2+ Complexes
Transient spectral hole-burning (THB), a powerful technique for probing the electronic structures of coordination compounds, is applied to the lowest excited 3MLCT states of specifically deuterated [Ru(bpy)3]2+ complexes doped into crystals of racemic [Zn(bpy)3](ClO4)2. Results are consistent with and complementary to conclusions reached from excitation-line-narrowing experiments. Two sets of 3MLCT transitions are observed in conventional spectroscopy of [Ru(bpy-d(n))(3-x)(bpy-d(m))(x)]2+ (x =...[Show more]
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