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Probing the Electronic Structures of Coordination Compounds by Transient Spectral Hole-Burning. Applications to Specifically Deuterated [Ru(bpy)3]2+ Complexes

Riesen, Hans; Wallace, Lynne; Krausz, Elmars


Transient spectral hole-burning (THB), a powerful technique for probing the electronic structures of coordination compounds, is applied to the lowest excited 3MLCT states of specifically deuterated [Ru(bpy)3]2+ complexes doped into crystals of racemic [Zn(bpy)3](ClO4)2. Results are consistent with and complementary to conclusions reached from excitation-line-narrowing experiments. Two sets of 3MLCT transitions are observed in conventional spectroscopy of [Ru(bpy-d(n))(3-x)(bpy-d(m))(x)]2+ (x =...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic0005386


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