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Chemoenzymatic approaches to the montanine alkaloids: a total synthesis of (+)-brunsvigine

Banwell, Martin; Kokas, Okanya; Willis, Anthony

Description

The readily available and enzymatically derived cis-1,2-dihydrocatechols 3a and 3b have been elaborated over 17 steps, including a novel radical addition/elimination sequence, into the enantiomer, (+)-1, of the montanine alkaloid brunsvigine [(-)-1].

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/33228
Source: Organic Letters
DOI: 10.1021/ol071344y

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