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Stereoselective association of binuclear metallacycles in coordination polymers

Khlobystov, Andrei N; Brett, Matthew T; Blake, Alexander J; Champness, Neil R; Gill, Peter; O'Neill, Darragh P; Teat, Simon J; Wilson, Claire; Schroeder, Martin


A series of structurally related binuclear metallacycles Cd(NO3)2L]2, where L is an angular exobidentate ligand, have been synthesized. Each metallacycle contains two coordinatively unsaturated, chiral metal centers within a single molecule, and the assembly of these metallacycles into polymeric framework structures has been studied systematically for the first time. Stereoselective homochiral association of [Cd(NO3)2L]2 leads to the formation of helical coordination polymers, whereas meso type...[Show more]

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja029048y


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