Stereoselective association of binuclear metallacycles in coordination polymers
A series of structurally related binuclear metallacycles Cd(NO3)2L]2, where L is an angular exobidentate ligand, have been synthesized. Each metallacycle contains two coordinatively unsaturated, chiral metal centers within a single molecule, and the assembly of these metallacycles into polymeric framework structures has been studied systematically for the first time. Stereoselective homochiral association of [Cd(NO3)2L]2 leads to the formation of helical coordination polymers, whereas meso type...[Show more]
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