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Synthesis, Structure, and Electrochemistry of Di- and Zerovalent Nickel, Palladium, and Platinum Monomers and Dimers Derived from an Enantiopure ( S , S )-Tetra(Tertiary Phosphine)

Kitto, Heather; Rae, A David; Webster, Richard; Willis, Anthony; Wild, Stanley (Bruce)

Description

The ligand (S,S)-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane, (S,S)-tetraphos, reacts with hexa(aqua)-nickel(II) chloride in the presence of trimethylsilyl triflate (TMSOTf) in dichloromethane to give the yellow square-planar complex [Ni{(R,R)-tetraphos}](OTf)2, which has been crystallographically characterized as the square-pyramidal, acetonitrile adduct [Ni(NCMe){(R,R)-tetraphos}]OTf. Cyclic voltammograms of the nickel(II) complex in dichloromethane and acetonitrile at 20°C showed...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/31806
Source: Inorganic Chemistry
DOI: 10.1021/ic700912q

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